ISSN: 1405-888X ISSN-e: 2395-8723
Study of the interaction of the compound monomercaptoundecahydro-closo-dodecaborate [B12H11SH]2- with Cu(II) using electrochemical and spectroscopic techniques
Vol. 14 No. 2 (2011), Original Articles
Vol. 14 No. 2 (2011)

Study of the interaction of the compound monomercaptoundecahydro-closo-dodecaborate [B12H11SH]2- with Cu(II) using electrochemical and spectroscopic techniques

Original Articles
https://doi.org/10.22201/fesz.23958723e.2011.2.49
Juan Carlos García-Ramos
Facultad de Química, UNAM
Jean-Michel Grévy M.
Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos
Narayan S. Hosmane
Department of Chemistry and Biochemistry, Northern Illinois University
Mario Altamirano-Lozano
Facultad de Estudios Superiores Zaragoza, Campus II, UNAM
Lena Ruiz-Azuara
Facultad de Química, UNAM
Luis Ortiz-Frade
Centro de Investigación y Desarrollo Tecnológico en Electroquímica
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Keywords

Cu(II)
spectrophotometry
monomercaptoundecahydro-closo-dodecaborate
cyclic voltammetry

How to Cite

García-Ramos, J. C., Grévy M., J.-M., Hosmane, N. S., Altamirano-Lozano, M., Ruiz-Azuara, L., & Ortiz-Frade, L. (2013). Study of the interaction of the compound monomercaptoundecahydro-closo-dodecaborate [B12H11SH]2- with Cu(II) using electrochemical and spectroscopic techniques. TIP Revista Especializada En Ciencias Químico-Biológicas, 14(2). https://doi.org/10.22201/fesz.23958723e.2011.2.49
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Abstract

In this paper we present spectroscopic and electrochemical studies of the chemical reaction between the salt Cu(NO3)2 2.5 H2O and the boron compound, monomercaptoundecahydro-closo-dodecaborate, [B12H11SH]2- in methanol. When the two substances were mixed a chemical reduction from Cu(II) to Cu(I) and an oxidation of the compound [B12H11SH]2- to [B12H11SSB12H11]4- were detected. The results obtained here may be useful in establishing a methodology to study the interaction of other metals with the compound [B12H11SH]2- in different solvents.

https://doi.org/10.22201/fesz.23958723e.2011.2.49
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